Product ID:ACCORD HERBICIDE
MSDS Date:08/01/1995
FSC:6840
NIIN:01-356-8892
Status Code:A
MSDS Number: CJSJH

Emergency Phone: 314-694-4000 (COLLECT)

Info Phone: 314-694-6338/800-332-3111

Preparer: NOT PROVIDED.

Cage: 76541

Telephone: 501-367-8561

Cage: 1HB45

GLYPHOSATE,N-(PHOSPHONOMETHYL)GLYCINE,IN

CAS: 38641-94-0

RTECS: MC1080000

INERT INGREDIENTS

Fraction By Weight: 58.5%

INERT INGREDIENTS

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Health Hazards Acute and Chronic:EYE CONTACT: ACCORD HERBICIDE IS NO
MORE THAN SLIGHTLY IRRITATING BASED ON TOXICIY STUDIES. SKIN
CONTACT: ACCORD HERBICIDE IS NO MORE THAN SLIGHTLY IRRITATING BASED
ON TOXICIY STUDIES. INGESTION:: ACC ORD HERBICIDE IS NO MORE THAN
SLIGHTLY TOXIC BASED ON TOXICIY STUDIES. NO SIGNIFICANT ADVERSE
HEALTH EFFECTS ARE EXPECTED TO DEVELOP IF ONLY SMALL AMOUNTS (LESS
THAN A MOUTHFUL) ARE SWALLOWED. INHALAT ION: ACCORD HERBICIDE IS NO
MORE THAN SLIGHTLY TOXIC IF INHALED BASED ON TOXICIY STUDIES.
Explanation of Carcinogenicity:NOT PROVIDED.
Effects of Overexposure:EYE CONTACT: ACCORD HERBICIDE IS NO MORE THAN
SLIGHTLY IRRITATING BASED ON TOXICIY STUDIES. SKIN CONTACT: ACCORD
HERBICIDE IS NO MORE THAN SLIGHTLY IRRITATING BASED ON TOXICIY
STUDIES. INGESTION:: ACC ORD HERBICIDE IS NO MORE THAN SLIGHTLY
TOXIC BASED ON TOXICIY STUDIES. NO SIGNIFICANT ADVERSE HEALTH
EFFECTS ARE EXPECTED TO DEVELOP IF ONLY SMALL AMOUNTS (LESS THAN A
MOUTHFUL) ARE SWALLOWED. INHALAT ION: ACCORD HERBICIDE IS NO MORE
THAN SLIGHTLY TOXIC IF INHALED BASED ON TOXICIY STUDIES.
Medical Cond Aggravated by Exposure:NOT PROVIDED.

First Aid:IF INHALED: REMOVE INDIVIDUAL TO FRESH AIR. SEEK MEDICAL
ATTENTION IF BREATHING DIFFICULTY DEVELOPS.

Flash Point Method:TCC
Flash Point:>93.3C, 200.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2, OTHER CLASS B
EXTINGUISHING AGENT.
Fire Fighting Procedures:FIREFIGHTERS & OTHERS THAT MAY BE EXPOSED TO
VAPORS/MIST/DUST/PRODUCTS OF COMBUSTION SHOULD WEAR FULL PROTECTIVE
CLOTHING & SELF-CONTAINED BREATHING APPARATUS. EQUIPMENT SHOULD BE
THOROUGHLY CLEANED A FTER USE.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:OBSERVE ALL PROTECTION AND SAFETY PRECAUTIONS
WHEN CLAENING UP SPILLS. SMALL SPILLS: (<1GALLON), SOAK UP WITH
TOWELS AND DISCARD IN TRASH. CLEAN AREA WITH SOAP AND WATER AND
RINSE THOROUGHLY. LARGE S PILL: DIKE AND ABSORB WITH BENTONITE OR
OTHER CLAYS. COLLECT AND PLACE IN A METAL DRUM FOR DISPOSAL.
THOROUGHLY SCRUB FLOOR WITH A STRONG INDUSTRIAL DETERGENT AND RINSE
WITH WATER.
Neutralizing Agent:NOT PROVIDED.

Handling and Storage Precautions:STORE ABOVE 10F (12C) TO KEEP FROM
CRYSTALLIZING. CRYSTALS WILL SETTLE TO THE BOTTOM. IF ALLOWED TO
CRYSTALLIZE, PLACE IN WARM ROOM 68F (20C) FOR SEVERAL DAYS TO
REDISSOLVE AND ROLL OR SHAKE CONTAINE R OR RECIRCULATE IN MINI-BULK
CONTAINERS TO MIX WELL BEFORE USING.
Other Precautions:DO NOT CONTAMINATE WATER WHEN DISPOSING OF EQUIPMENT
WASHWATERS. DO NOT CONTAMINATE FOODSTUFFS, FEED OR SEED BY STORAGE
OR DISPOSAL. KEEP OUT OF REACH OF CHILDREN. CAUT!ION! HARMFUL IF
INHALED. REFORM ULATION IS PROHIBITED.

Respiratory Protection:AVOID BREATHING MIST OR VAPOR.THIS PRODUCT IS
NOT LIKELY TO POSE AIRBORNE EXPOSURE CONCERN WHEN HANDLED & USED IN
ACCORDANCE WITH LABEL INSTRUCTIONS.
Ventilation:NO SPECIAL PRECAUTIONS ARE RECOMMENDED.
Protective Gloves:MINIMIZE SKIN CONTAMINATION BY FOLLOWING GOOD
HANDLING PRACTICES.
Eye Protection:USE GOOD HANDLING PRACTICES TO AVOID EYE CONTACT.
Other Protective Equipment:APPLICATORS/OTHER HANDLERS MUST WEAR:LONG
SLEEVED SHIRT, LONG PANTS, AND SHOES W/ITH SOCKS.
Work Hygienic Practices:WASH HANDS AND CONTAMINATED SKIN THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
NONE

HCC:V5
Boiling Pt:B.P. Text:NOT PROVIDED.
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NOT PROVIDED.
Vapor Density:NP
Spec Gravity:1.158
pH:4.6 - 4.8
Viscosity:NOT PROVIDED.
Evaporation Rate & Reference:NOT PROVIDED.
Solubility in Water:NOT PROVIDED.
Appearance and Odor:COLORLESS SOLUTION, ESSENTIALLY ODORLESS
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
GALVANIZED OR UNLINED STEE; IT MAY FORM HYDROGEN GAS. CAN REACT WITH
CAUSTIC OR BASIC MATERIALS.
Stability Condition to Avoid:OPEN FLAME,SPARK,WELDER'S TORCH,LIGHTED
CIGARETTE OR OTHER IGNITION SOURCE.
Hazardous Decomposition Products:NONE KNOWN.

Waste Disposal Methods:WASTE THAT CANNOT BE USED OR CHEMICALLY
REPROCESSED SHOULD BE DISPOED OF IN A LANDFILL APPROVED FOR
PESTICIDE DISPOSAL OR IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE
OR LOCAL PROCEDURES. EMPTY CONTAI NER RETAINS VAPOR AND PRODUCT
RESIDUE. OBSERVE ALL LABEL SAFEGUARD UNTIL CONTAINER IS CLEANED OR
DES TROYED. DO NOT REUSE THEM.

Toxicological Information:LD50 (ORAL, RAT) > 5,000 MG/KG; FIFRA
CATEGORY IV DERMAL- RABBIT LD50 - > 5000 MG/KG FIFRA CATEGORY IV
INHALATION - RAT 4-HR LC50- >1.3 MG/L, THE HIGHEST ATMOSPHERIC
CONCENTRATION ACHIEVABLE IN THIS STUDY; FIFRA CATEGORY III EYE
IRRITATION - RABBIT (6 ANIMALS), 24-HR OXP.; FIFRA CATEGORY IV
SKIN IRRITATION - RABBIT (6 ANIMALS), 24-HR OXP.; FIFRA CATEGORY
IV. IN REPEAT DOSING STUDIES (6-MONTH ), DOGS FED MON 0139
EXHIBITED SLIGHT BODY WEIGHT CHANGES.

Ecological:96-HR LC50 BLUEGILL: >1,000 MG/L- PRACTICALLY NONTOXIC.
96-HR LC50 TROUT: >1,000 MG/L- PRACTICALLY NONTOXIC. 48-HR EC50
DAPHNIA: 930 MG/L- PRACTICALLY NONTOXIC.

Transport Information:DOT PROPER SHIPPING NAME, HAZARD CLASS/ID NO,
LABEL: NOT APPLICABLE.

SARA Title III Information:NOT APPLICABLE.
Federal Regulatory Information:EPA REG#:524-326. ALL COMPONENTS ARE ON
THE US EPA'S TSCA INVENTORY LIST.
State Regulatory Information:NOT PROVIDED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.